Nonheme oxoiron(iv) complexes of pentadentate N5 ligands: spectroscopy, electrochemistry, and oxidative reactivity
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چکیده
منابع مشابه
Nonheme Oxoiron(IV) Complexes of Pentadentate N5 Ligands: Spectroscopy, Electrochemistry, and Oxidative Reactivity.
Oxoiron(IV) species have been found to act as the oxidants in the catalytic cycles of several mononuclear nonheme iron enzymes that activate dioxygen. To gain insight into the factors that govern the oxidative reactivity of such complexes, a series of five synthetic S = 1 [Fe(IV)(O)(L(N5))](2+) complexes has been characterized with respect to their spectroscopic and electrochemical properties a...
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در این مطالعه بر هم کنش این چهار کمپلکس با dna تیموس گوساله توسط روش های اسپکتروفتومتری، فلوریمتری، دو رنگ نمائی دورانی، و ویسکوزیمتری بررسی شدند تا اثر استخلاف های متیل بر روی لیگاندهای فنانترولین بررسی گردد.
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ژورنال
عنوان ژورنال: Chem. Sci.
سال: 2013
ISSN: 2041-6520,2041-6539
DOI: 10.1039/c2sc21318d